Issue 15, 2023

Synthesis of a rhodium(iii) dinitrogen complex using a calix[4]arene-based diphosphine ligand

Abstract

The synthesis and characterisation of the rhodium(III) dinitrogen complex [Rh(2,2′-biphenyl)(CxP2)(N2)]+ are described, where CxP2 is a trans-spanning calix[4]arene-based diphosphine and the dinitrogen ligand is projected into the cavity of the macrocycle.

Graphical abstract: Synthesis of a rhodium(iii) dinitrogen complex using a calix[4]arene-based diphosphine ligand

Supplementary files

Article information

Article type
Communication
Submitted
15 Dec 2022
Accepted
23 Jan 2023
First published
23 Jan 2023
This article is Open Access
Creative Commons BY license

Chem. Commun., 2023,59, 2150-2152

Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand

J. Emerson-King, S. Pan, M. R. Gyton, R. Tonner-Zech and A. B. Chaplin, Chem. Commun., 2023, 59, 2150 DOI: 10.1039/D2CC06837K

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