Issue 37, 2022

n-Type conjugated polymers comprising bithiophene imide and multifluorinated thiophene moieties synthesized by direct arylation polycondensation

Abstract

We synthesized four n-type conjugated polymers comprising a bithiophene imide (BTI) unit and 3,3′,4,4′-tetrafluoro-2,2′-bithiophene (4FBT) or (E)-1,2-bis(3,4-difluorothien-2-yl)ethene (4FTVT) via direct arylation polycondensation, and comprehensively studied the optical, electrochemical and charge transport properties of the polymers. Increasing the BTI acceptor unit from one to two in the repeating unit slightly decreased the frontier molecular orbital levels of the polymers and blue-shifted their absorption spectra. Moreover, this change altered the molecular packing from an edge-on backbone orientation to bimodal packing with mixed edge-on and face-on orientations. When used as semiconductor layers in organic thin-film transistors, all four polymers exhibited unipolar n-type transport behavior with the highest saturation and a linear electron mobility of 0.72 and 0.67 cm2 V−1 s−1, respectively. Our findings suggest that direct arylation polycondensation can serve as an ecofriendly protocol for the synthesis of high-performance n-type conjugated polymers based on BTI through careful molecular design.

Graphical abstract: n-Type conjugated polymers comprising bithiophene imide and multifluorinated thiophene moieties synthesized by direct arylation polycondensation

Supplementary files

Article information

Article type
Paper
Submitted
22 Feb 2022
Accepted
03 Jun 2022
First published
07 Jun 2022

J. Mater. Chem. C, 2022,10, 13905-13912

n-Type conjugated polymers comprising bithiophene imide and multifluorinated thiophene moieties synthesized by direct arylation polycondensation

H. Cai, X. Zhang, Y. Shi, C. Xu, T. Wang, C. Wang, T. Du, Y. Deng and Y. Geng, J. Mater. Chem. C, 2022, 10, 13905 DOI: 10.1039/D2TC00732K

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