Effect of interfacial rheology on drop coalescence in water–oil emulsion

Abstract

Over the last years several studies have been conducted to understand emulsion formation and its behavior. In some applications, the aim is the phase separation of the emulsions through the coalescence of the drops, as in the oil industry. In this study, the relationship between rheological properties of oil–water interfaces and the drainage time of a thin oil film between two aqueous drops was investigated. Interfacial tension and dilatational rheology were measured using the axisymmetric drop shape analysis. We evaluated different concentrations of a nonionic surfactant (Span 80) dissolved in mineral oil (Primol 352) phase. The results indicate a direct relationship between the properties of the structure formed at the oil–water interface and the absence of droplet coalescence. For low surfactant concentrations, below the critical micelle concentration (CMC), the interface is weakly elastic (fluid-like) and the coalescence process always occurs; the draining time is not to related to the aging time of the interface. For surfactant concentrations above CMC, the elastic and viscous moduli showed significant changes with aging leading to the formation of a solid-like film at the interface preventing further coalescence. We used the characteristic times of change in interfacial rheological behavior to better explain the non-coalescence process.