Issue 48, 2022, Issue in Progress

One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation

Abstract

Chlorocarboxylation of toluene was achieved by photoirradiation of a chlorine dioxide radical (ClO2˙) under ambient conditions (298 K and 1 atm). 2- and 4-Chlorobenzoic acids were obtained in a 1 : 1 yield ratio. This is a single step synthesis under metal-free and mild conditions.

Graphical abstract: One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation

Supplementary files

Article information

Article type
Paper
Submitted
19 Oct 2022
Accepted
21 Oct 2022
First published
02 Nov 2022
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2022,12, 31412-31414

One-pot chlorocarboxylation of toluenes with chlorine dioxide under photoirradiation

S. Ohno, H. Asahara, T. Inoue and K. Ohkubo, RSC Adv., 2022, 12, 31412 DOI: 10.1039/D2RA06591F

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