Electrochemical performance of CoSe2 with mixed phases decorated with N-doped rGO in potassium-ion batteries

Abstract

Potassium-ion batteries (PIBs) have received much attention as next-generation energy storage systems because of their abundance, low cost, and slightly lower standard redox potential than lithium-ion batteries (LIBs). Nevertheless, they still face great challenges in the design of the best electrode materials for applications. Herein, we have successfully synthesized nano-sized CoSe₂ encapsulated by N-doped reduced graphene oxide (denoted as CoSe₂@N-rGO) by a direct one-step hydrothermal method, including both orthorhombic and cubic CoSe₂ phases. The CoSe₂@N-rGO anodes exhibit a high reversible capacity of 599.3 mA h g⁻¹ at 0.05 A g⁻¹ in the initial cycle, and in particular, they also exhibit a cycling stability of 421 mA h g⁻¹ after 100 cycles at 0.2 A g⁻¹. Density functional theory (DFT) calculations show that CoSe₂ with N-doped carbon can greatly accelerate electron transfer and enhance the rate performance. In addition, the intrinsic causes of the higher electrochemical performance of orthorhombic CoSe₂ than that of cubic CoSe₂ are also discussed.