Synthesis of an Fe(terpy-cage)2 dumbbell

Frederic Dournel; Massoud Koshan; Philipp Woite; Michael Roemelt; Matthias Otte

doi:10.1039/D1RA08994C

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Synthesis of an Fe(terpy-cage)₂ dumbbell†

Frederic Dournel,‡^a Massoud Koshan,‡^a Philipp Woite,^b Michael Roemelt

*^b and Matthias Otte

*^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie, Universität Göttingen, Tammannstraße 4, 37077 Göttingen, Germany
E-mail: matthias.otte@chemie.uni-goettingen.de

^b Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor Str. 2, 12489 Berlin, Germany
E-mail: michael.roemelt@hu-berlin.de

Abstract

An azide masked amine is used to obtain a cage of lower symmetry that possess one terpy-group in an exo-position. This group can coordinate to iron(II), yielding selectively an easy to purify Fe(terpy-cage)₂ dumbbell. The dumbbell can also be obtained in a one pot reaction, which proceeded without isolation of the exo-functionalized cage.

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Article information

DOI: https://doi.org/10.1039/D1RA08994C
Article type: Paper
Submitted: 11 Dec 2021
Accepted: 17 Jan 2022
First published: 26 Jan 2022
This article is Open Access

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RSC Adv., 2022,12, 3402-3405

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Synthesis of an Fe(terpy-cage)₂ dumbbell

F. Dournel, M. Koshan, P. Woite, M. Roemelt and M. Otte, RSC Adv., 2022, 12, 3402 DOI: 10.1039/D1RA08994C

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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