Facile and green preparation of solid carbon nanoonions via catalytic co-pyrolysis of lignin and polyethylene and their adsorption capability towards Cu(ii)

Abstract

Carbon nanomaterials, such as carbon nanoonions (CNOs), possess promising applications in various fields. There are urgent demands to synthesize carbon nanomaterials from a green and renewable carbon source. In this study, solid CNOs with relatively uniform size distribution (with diameters of about 30–50 nm), abundant structure defects and oxygen-containing surface functional groups (such as –OH and –COOH) are developed from co-pyrolysis of lignin (LG) and polyethylene (PE) in the presence of Ni-based catalysts. The type of catalyst, the concentration of catalyst and catalytic co-pyrolysis temperature play important roles in the morphologies and properties of CNOs as confirmed by TEM and SEM. Furthermore, the produced CNOs can act as a low-cost and highly-efficient adsorbent to remove Cu(II) from aqueous solution according to a homogeneous monolayer, chemical action-dominated, endothermic and spontaneous process. The theoretical maximum adsorption capacity of CNOs calculated from the Langmuir model is 100.00 mg g⁻¹. Surface deposition, complexation, π electron–cation interaction and electrostatic interaction are responsible for the adsorption of Cu(II) using the prepared CNOs.