Palladium-catalyzed decarboxylative O-allylation of phenols with γ-methylidene-δ-valerolactones†
Daoshan
Yang 
a
and
Jian
Lv
*a
a
and
Jian
Lv
*a
Abstract
A novel palladium-catalyzed decarboxylative O-allylation of phenols was developed, in which a γ-methylidene-δ-valerolactone (GMDV) was found to be an efficient and selective allylation reagent, affording the target allyl phenyl ethers in up to 92% yields under mild conditions.
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