Photomediated RAFT step-growth polymerization was performed with and without the presence of a photocatalyst using a trithiocarbonate-based CTA and a maleimide monomer. Under catalyst-free conditions, the polymerization proceeded with an appreciable rate under irradiation with blue and green light, which was extended to red light in the presence of ZnTPP.
S. M. Clouthier, J. Tanaka and W. You, Polym. Chem., 2022, 13, 6114 DOI: 10.1039/D2PY01166B
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