Issue 27, 2022
From the journal:

Polymer Chemistry

Thioanhydride/isothiocyanate/epoxide ring-opening terpolymerisation: sequence selective enchainment of monomer mixtures and switchable catalysis†

Dorothee Silbernagl, ORCID logo a   Heinz Sturm ORCID logo a  and  Alex J. Plajer ORCID logo *b  

* Corresponding authors

a BAM Bundesanstalt für Materialforschung und -Prüfung, Unter den Eichen 87, 12205 Berlin, Germany

b Intitut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstraße 34-36, 14195 Berlin, Germany
E-mail: plajer@zedat.fu-berlin.de

Abstract

We report a new sequence selective terpolymerisation in which three monomers (butylene oxide (BO) A, PhNCS B and phtalic thioanhydride (PTA) C) are selectively enchained into an (ABA′C)n sequence. PTA/PhNCS/BO ring-opening terpolymerisation ROTERP can be coupled with CS2 ROTERP to generate tetrapolymers and with εDL ROP in switchable catalysis for blockpolymer synthesis.

Graphical abstract: Thioanhydride/isothiocyanate/epoxide ring-opening terpolymerisation: sequence selective enchainment of monomer mixtures and switchable catalysis

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D2PY00629D
Article type
Communication
Submitted
16 May 2022
Accepted
16 Jun 2022
First published
20 Jun 2022
This article is Open Access
Creative Commons BY-NC license

Polym. Chem., 2022,13, 3981-3985

Permissions

Request permissions

Thioanhydride/isothiocyanate/epoxide ring-opening terpolymerisation: sequence selective enchainment of monomer mixtures and switchable catalysis

D. Silbernagl, H. Sturm and A. J. Plajer, Polym. Chem., 2022, 13, 3981 DOI: 10.1039/D2PY00629D

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements