Issue 48, 2022
From the journal:

Organic & Biomolecular Chemistry

Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for electron-transfer- and energy-transfer-driven reactions†

Tatsuya Morofuji, ORCID logo *a   Takuma Kurokawa,a   Youhei Chitose, ORCID logo bc   Chihaya Adachibd  and  Naokazu Kano ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan
E-mail: tatsuya.morofuji@gakushuin.ac.jp, naokazu.kano@gakushuin.ac.jp

b Center for Organic Photonics and Electronics Research (OPERA), Kyushu University, 744 Motooka, Nishi, Fukuoka 819-0395, Japan

c Department of Applied Chemistry, Graduate School of Engineering, Center for Molecular Systems (CMS), Kyushu University, Fukuoka 819-0395, Japan

d International Institute for Carbon Neutral Energy Research (I2CNER), Kyushu University, Fukuoka 819-0395, Japan

Abstract

In this study, we propose that the trifluoromethylated thermally activated delayed fluorescent molecule 4[Cz(CF3)2]IPN is a versatile organic photocatalyst that can be used for electron-transfer-driven reactions requiring a photocatalyst with high oxidizing power and energy-transfer-driven reactions that require an Ir photocatalyst. 4[Cz(CF3)2]IPN was used in radical reactions via electron transfer and dearomative cycloaddition reactions via energy transfer.

Graphical abstract: Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for electron-transfer- and energy-transfer-driven reactions

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Article information

DOI
https://doi.org/10.1039/D2OB02055F
Article type
Communication
Submitted
09 Nov 2022
Accepted
15 Nov 2022
First published
16 Nov 2022

Org. Biomol. Chem., 2022,20, 9600-9603

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Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for electron-transfer- and energy-transfer-driven reactions

T. Morofuji, T. Kurokawa, Y. Chitose, C. Adachi and N. Kano, Org. Biomol. Chem., 2022, 20, 9600 DOI: 10.1039/D2OB02055F

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