Optically active polymer particles with programmable surface microstructures constructed using chiral helical polyacetylene

Abstract

Micro/nanoparticles with surface microstructures have attracted tremendous attention due to their fascinating structures and properties. Herein, we present the first strategy for producing optically active polymer particles with varying surface microstructures via a template surface modification process in which achiral particles act as the template and helical substituted polyacetylene acts as the chiral component. To prepare the designed chiral-functionalized particles, template particles were first reacted with propargylamine to produce alkynylated template particles. The alkynylated templates further participated in the polymerization of chiral alkyne monomers through a surface grafting precipitation polymerization approach, resulting in achiral particles with surface microstructures covalently bonded with a chiral helical polymer. SEM images ascertain the production of chiral-functionalized particles showing various shapes (jar-like, golf ball-like, and raspberry-like particles). Furthermore, CD and UV-vis absorption spectra demonstrate that the grafted polyacetylene chains adopt a predominantly single-handed helical conformation, thereby affording composite particles with optical activity. Using the established protocol, numerous advanced chiral-functionalized micro/nanostructures are expected to be designed and constructed.