In situ bridging nanotwinned all-solid-state Z-scheme g-C3N4/CdCO3/CdS heterojunction photocatalyst by metal oxide for H2 evolution

Abstract

Nanotwin and all-solid-state (ASS) Z-scheme heterojunction engineering are two widely used strategies for improving photocatalytic activity in H₂ production. However, both strategies fail to produce a satisfactory effect when used alone due to their own limitations. Hence, combining nanotwin and ASS Z-scheme heterojunction engineering is expected to improve photocatalytic activity effectively. Herein, we report a nanotwinned ASS Z-scheme g-C₃N₄/CdCO₃/CdS (CN/CC/CS) photocatalyst synthesized for the first time by in situ bridging of (CN) and (CS) with a (CC) conductor. The growth and ripening of CN/CC/CS are limited by thiourea (Tu) and CN. CN/CC/CS can improve charge carrier separation and transfer kinetics due to the synergetic advantages of its nanotwin structure, ASS Z-scheme junction, N–Cd chemically bonded interfaces, in situ intimate contact, and hierarchical architecture. The visible-light-driven H₂ production rate of CN/CC/CS is 345% of that of CN/CS. This work proposes a new method for rationally designing novel materials with improved photocatalytic activity by combining heterojunction and defect engineering.