Issue 7, 2022
From the journal:

New Journal of Chemistry

Transition-metal doped titanium-oxo clusters with diverse structures and tunable photochemical properties†

Dongchun Zheng,‡a   Xiao-Li Zhao, ORCID logo ‡b   Xueqi Yan,a   Weimin Xuan, ORCID logo c   Qi Zheng, ORCID logo *a   Lianjun Wang ORCID logo ad  and  Wan Jiangae  

* Corresponding authors

a State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, P. R. China
E-mail: qi.zheng@dhu.edu.cn

b Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062, P. R. China

c College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China

d Engineering Research Center of Advanced Glasses Manufacturing Technology, Ministry of Education, Donghua University, Shanghai 201620, P. R. China

e Institute of Functional Materials, Donghua University, Shanghai 201620, P. R. China

Abstract

A family of transition-metal doped Ti-oxo clusters with diverse core structures have been synthesized. Their photocurrent responses can be tuned by varying the heterometals, and the cobalt-doped cluster exhibits the highest H2 evolution activity (32.5 μmol g−1 h−1) with good stability.

Graphical abstract: Transition-metal doped titanium-oxo clusters with diverse structures and tunable photochemical properties

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Article information

DOI
https://doi.org/10.1039/D1NJ05532A
Article type
Communication
Submitted
19 Nov 2021
Accepted
13 Jan 2022
First published
15 Jan 2022

New J. Chem., 2022,46, 3083-3086

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Transition-metal doped titanium-oxo clusters with diverse structures and tunable photochemical properties

D. Zheng, X. Zhao, X. Yan, W. Xuan, Q. Zheng, L. Wang and W. Jiang, New J. Chem., 2022, 46, 3083 DOI: 10.1039/D1NJ05532A

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