A high sensitivity acetone gas sensor based on polyaniline–hydroxypropyl methylcellulose core–shell-shaped nanoparticles

Abstract

Core–shell-shaped nanoparticles (CSS-NPs) with polyaniline emeraldine salts (PANi) in the core and hydroxypropyl methylcellulose (HPMC) and heptadecafluorooctanesulfonic acid (C8F) shells, i.e., C8F-doped PANi@HPMC CSS-NPs, were synthesized as a gaseous acetone sensing material with high sensitivity and humidity stability. The HPMC was chemically combined on the positively charged PANi NPs' outer surface, allowing it to efficiently detect acetone gas at concentrations as low as 50 ppb at 25 °C. To impart humidity stability, C8F was employed as a hydrophobic dopant, and a valid signal could be reliably detected even in the range of 0–80% relative humidity. The sensing material's structural analysis was conducted using scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and infrared spectroscopy, and in particular, the reaction mechanism with acetone gas was detected through a spectroscopic method. Thus, these findings illustrate the potential as a novel sensing material to detect acetone gas at a trace level of less than 1 ppm in human respiratory gas.