Slow magnetic relaxation in Fe(ii) m-terphenyl complexes

Abstract

Two-coordinate transition metal complexes are exciting candidates for single-molecule magnets (SMMs) because their highly axial coordination environments lead to sizeable magnetic anisotropy. We report a series of five structurally related two-coordinate Fe(II) m-terphenyl complexes (4-R-2,6-Xyl₂C₆H₂)₂Fe [R = tBu (1), SiMe₃ (2), H (3), Cl (4), CF₃ (5)] where, by changing the functionalisation of the para-substituent (R), we alter their magnetic function. All five complexes are field-induced single-molecule magnets, with relaxation rates that are well-described by a combination of direct and Raman mechanisms. By using more electron donating R groups we were able to slow the rate of magnetic relaxation. Our ab initio calculations predict a large crystal field splitting (>850 cm⁻¹) and sizeable zero-field splitting parameters (ca. −60 cm⁻¹, |E| < 0.2 cm⁻¹) for 1–5. These favourable magnetic properties suggest that m-terphenyl ligands have untapped potential as chemically versatile ligands able to impose highly axial crystal fields.