Issue 19, 2022
From the journal:

Dalton Transactions

Identification of complexes of Nd(iii) with dithiophosphinic acids verifying the difference in complexation between Ln(iii) and An(iii)†

Qiling Guo, ORCID logo a   Tuo Fang,a   Qian Liu, ORCID logo a   Liyang Zhu, ORCID logo a   Suliang Yang ORCID logo *a  and  Guoxin Tian ORCID logo *ab  

* Corresponding authors

a Department of Radiochemistry, China Institute of Atomic Energy, Beijing 102413, China
E-mail: ysl79@ciae.ac.cn, gtian@ciae.ac.cn

b Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

Abstract

Five complex species of Nd(III) with HA have been spectroscopically and compositionally identified as NdA3, NdA3(HA), NdA3(HA)H2O, NdA3(H2O)3, and Nd(H2O)23·3A (HA, bis(2,4,4-trimethylpentyl)dithiophosphinic acid) with the help of X-ray diffraction analysis on single crystals of Nd(H2O)9·H2O·3B (HB = bis(iso-butyl)dithiophosphinic acid.

Graphical abstract: Identification of complexes of Nd(iii) with dithiophosphinic acids verifying the difference in complexation between Ln(iii) and An(iii)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D2DT00625A
Article type
Communication
Submitted
27 Feb 2022
Accepted
29 Mar 2022
First published
02 Apr 2022

Dalton Trans., 2022,51, 7416-7419

Permissions

Request permissions

Identification of complexes of Nd(III) with dithiophosphinic acids verifying the difference in complexation between Ln(III) and An(III)

Q. Guo, T. Fang, Q. Liu, L. Zhu, S. Yang and G. Tian, Dalton Trans., 2022, 51, 7416 DOI: 10.1039/D2DT00625A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements