Issue 10, 2022
From the journal:

Dalton Transactions

Metalloligand-based coordination polymer embedding the nitrosyl ruthenium complex for photoactive materials with bound nitric oxide†

Vasily Vorobyev, ORCID logo *a   Anastasia M. Cheplakova, ORCID logo a   Elena D. Stolyarova, ORCID logo a   Vladislav Yu. Komarova  and  Gennadiy A. Kostin ORCID logo a  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, Novosibirsk 630090, Russia
E-mail: vasily.vorob@gmail.com

Abstract

The stability of a photoactivated isonitrosyl state was boosted by confining a pre-designed bicarboxylate ligand with a ruthenium nitrosyl fragment in a 2D metal–organic framework. The novel Zn/Ru-based MOF, {Zn[RuNO(H2O)(inic)2(OH)2]2}·12H2O (inic = isonicotinate), was obtained with enhanced isonitrosyl stability by 30 K (up to 200 K) compared to the related ruthenium-only complex.

Graphical abstract: Metalloligand-based coordination polymer embedding the nitrosyl ruthenium complex for photoactive materials with bound nitric oxide

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Article information

DOI
https://doi.org/10.1039/D1DT03943A
Article type
Paper
Submitted
22 Nov 2021
Accepted
02 Feb 2022
First published
02 Feb 2022

Dalton Trans., 2022,51, 3954-3963

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Metalloligand-based coordination polymer embedding the nitrosyl ruthenium complex for photoactive materials with bound nitric oxide

V. Vorobyev, A. M. Cheplakova, E. D. Stolyarova, V. Yu. Komarov and G. A. Kostin, Dalton Trans., 2022, 51, 3954 DOI: 10.1039/D1DT03943A

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