A study on structural, optical, and electrical characteristics of perovskite CsPbBr3 QD/2D-TiSe2 nanosheet based nanocomposites for optoelectronic applications

Abstract

Lead halide perovskite (CsPbBr₃) quantum dots (QDs) and two-dimensional (2D) layered transition metal dichalcogenides have a significant application in solution-processed optoelectronic devices. Here, we report the oleylamine-assisted exfoliation of TiSe₂ nanosheets (NSs) in dichlorobenzene with high concentration and stable dispersion. The functionalized TiSe₂ NSs were used to synthesize the solution-processed perovskite CsPbBr₃ QD/TiSe₂ NS-based nanocomposite. The perovskite QDs and TiSe₂ NSs were characterized by different techniques. The strong photoluminescence (PL) quenching and decreased lifetime decay of the nanocomposite indicates efficient charge transfer from photo-excited CsPbBr₃ to TiSe₂ NSs. The calculated charge-transfer rate constant (K_ET) from photo-excited CsPbBr₃ to TiSe₂ NSs increased from 1.50 × 10⁸ to 2.79 × 10⁸ s⁻¹ in different concentrations of TiSe₂ NSs (5 to 20 μg mL⁻¹), respectively. Furthermore, the photo-currents of CsPbBr₃ QD/TiSe₂ NS nanocomposite devices were dramatically enhanced ∼2 times compared to pristine CsPbBr₃ QD based devices, which supports the charge transfer and charge separation in nanocomposite devices.