Issue 16, 2022

Charge transport in the spatially correlated exponential random energy landscape: effect of the nonpositive correlation function

Abstract

Charge transport in amorphous semiconductors having spatially correlated exponential density of states (DOS) has been considered for the arbitrary behavior of the correlation function of random energies. Average carrier velocity is exactly calculated for the quasi-equilibrium (nondispersive) transport regime. For the symmetric exponential DOS with exponential tails for low and high energies and nonpositive correlation function the temperature of the transition to the dispersive transport regime depends on correlation properties and becomes greater than the traditional estimation based on the DOS decay energy kT = U0. Another new feature of the transport in the landscape having nonpositive correlation function is the decrease of the mobility with the field in the low field region and development of the universal mobility field dependence for stronger fields.

Graphical abstract: Charge transport in the spatially correlated exponential random energy landscape: effect of the nonpositive correlation function

Article information

Article type
Paper
Submitted
01 Nov 2021
Accepted
28 Mar 2022
First published
30 Mar 2022

Phys. Chem. Chem. Phys., 2022,24, 9534-9542

Charge transport in the spatially correlated exponential random energy landscape: effect of the nonpositive correlation function

S. Novikov, Phys. Chem. Chem. Phys., 2022, 24, 9534 DOI: 10.1039/D1CP04991G

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