In this work, we introduce trimethylbromosilane (C3H9SiBr), which can protect lithium metal anodes via an in situ formed SEI layer while catalyzing the decomposition of Li2O2. As a result, lithium–oxygen batteries with C3H9SiBr offer a long cycle life of 110 cycles with a significantly reduced charging/discharging overpotential.
C. Li, M. Wu, W. Chen, Y. Rong, Q. Wang and X. Zhang, Chem. Commun., 2022, 58, 13632 DOI: 10.1039/D2CC05118D
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