Issue 87, 2022

A homoleptic tris(diphosphacyclobutadiene) tripledecker sandwich complex

Abstract

The synthesis and characterisation of [Co24-P2C2tBu2)2(μ:η44-P2C2tBu2)] (1) is described, featuring two cobalt atoms and three diphosphacyclobutadiene ligands. This compound is the first triple-decker sandwich complex which exclusively contains cyclobutadiene ligands.

Graphical abstract: A homoleptic tris(diphosphacyclobutadiene) tripledecker sandwich complex

Supplementary files

Article information

Article type
Communication
Submitted
18 Aug 2022
Accepted
19 Sep 2022
First published
24 Sep 2022

Chem. Commun., 2022,58, 12212-12215

A homoleptic tris(diphosphacyclobutadiene) tripledecker sandwich complex

C. Rödl, G. Hierlmeier and R. Wolf, Chem. Commun., 2022, 58, 12212 DOI: 10.1039/D2CC04601F

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