Issue 91, 2022
From the journal:

Chemical Communications

Phenylphosphonic acid as a grain-refinement additive for a stable lithium metal anode†

Pinjuan Zou,a   Jun Liu, ORCID logo a   Zhenguo Huang, ORCID logo *b   Renzong Hu ORCID logo a  and  Liuzhang Ouyang ORCID logo *ac  

* Corresponding authors

a School of Materials Science and Engineering and Key Laboratory of Advanced Energy Storage Materials of Guangdong Province, South China University of Technology, Guangzhou, 510641, People's Republic of China
E-mail: meouyang@scut.edu.cn

b School of Civil and Environmental Engineering, University of Technology Sydney, Sydney, NSW, Australia
E-mail: zhenguo.huang@uts.edu.au

c China-Australia Joint Laboratory for Energy & Environmental Materials and Key Laboratory of Fuel Cell Technology of Guangdong Province, Guangzhou 510641, People's Republic of China

Abstract

Phenylphosphonic acid (PPOA) has been proposed as a new additive for carbonate electrolytes, in which the complexation reaction between PPOA and Li+ reduces the nucleus size and boosts the nucleation quantity during the plating process. Thus, enhanced cycling stability is obtained in both symmetric cells and full cells.

Graphical abstract: Phenylphosphonic acid as a grain-refinement additive for a stable lithium metal anode

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Article information

DOI
https://doi.org/10.1039/D2CC04504D
Article type
Communication
Submitted
13 Aug 2022
Accepted
17 Oct 2022
First published
17 Oct 2022

Chem. Commun., 2022,58, 12724-12727

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Phenylphosphonic acid as a grain-refinement additive for a stable lithium metal anode

P. Zou, J. Liu, Z. Huang, R. Hu and L. Ouyang, Chem. Commun., 2022, 58, 12724 DOI: 10.1039/D2CC04504D

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