Issue 83, 2022
From the journal:

Chemical Communications

Nickel(ii)-catalyzed highly selective 1,2-diborylation of non-activated monosubstituted alkenes†

Zhi-Kai Zhang,‡a   Ya-Li Feng,‡b   Zheng Ruan,a   Yuan-Qing Xu,a   Zhong-Yan Cao, ORCID logo *a   Meng-Hua Li*a  and  Chao Wang ORCID logo *c  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China
E-mail: zycao@henu.edu.cn, limh@henu.edu.cn

b School of Pharmacy and Chemical Engineering, Zhengzhou University of Industrial Technology, Zhengzhou, China

c Tianjin Key Laboratory of Structure and Performance for Functional Molecules, College of Chemistry, Tianjin Normal University, Tianjin 300387, China
E-mail: chwang@tjnu.edu.cn

Abstract

A practical method for 1,2-diborylation of non-activated monosubstituted alkenes via nickel catalysis has been developed. The protocol features high functional group tolerance and can be applied for the formal synthesis of drugs and modification of natural product derivatives. Preliminary mechanistic studies imply the involvement of a Ni(II) catalytic cycle.

Graphical abstract: Nickel(ii)-catalyzed highly selective 1,2-diborylation of non-activated monosubstituted alkenes

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Article information

DOI
https://doi.org/10.1039/D2CC04382C
Article type
Communication
Submitted
05 Aug 2022
Accepted
21 Sep 2022
First published
21 Sep 2022

Chem. Commun., 2022,58, 11709-11712

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Nickel(II)-catalyzed highly selective 1,2-diborylation of non-activated monosubstituted alkenes

Z. Zhang, Y. Feng, Z. Ruan, Y. Xu, Z. Cao, M. Li and C. Wang, Chem. Commun., 2022, 58, 11709 DOI: 10.1039/D2CC04382C

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