Issue 50, 2022
From the journal:

Chemical Communications

Perovskite-derived structure modulation in the iron sulfate family†

Yuanqi Lan,‡ab   Qi Yan,‡ac   Xinyuan Zhang,d   Wenjiao Yao,*a   Chenchen Wang,e   Chun-Sing Lee, ORCID logo e   Philip Lightfoot ORCID logo *f  and  Yongbing Tang ORCID logo *ab  

* Corresponding authors

a Advanced Energy Storage Technology Research Center, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China
E-mail: wj.yao@siat.ac.cn, tangyb@siat.ac.cn

b Shenzhen College of Advanced Technology, University of Chinese Academy of Sciences, Shenzhen 518055, China

c Nano Science and Technology Institute, University of Science and Technology of China, Suzhou, China

d Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystals, Tianjin University of Technology, Tianjin 300384, China

e Center of Super-Diamond and Advanced Films and Department of Chemistry, City University of Hong Kong, Hong Kong SAR, P. R. China

f School of Chemistry and EaStChem, University of St Andrews, St Andrews, Fife, UK
E-mail: pl@st-andrews.ac.uk

Abstract

We report the first example of a perovskite sulfate [Na3(H2O)]Fe(SO4)3. Further structure modulation, by dimensional reduction or ligand extension, has resulted in two related layered perovskite-like compounds Na6Fe(SO4)4 and Na12Fe3(SO4)6F8. Taken together, these results open up a more general strategy for the future design of more complex perovskite-related materials.

Graphical abstract: Perovskite-derived structure modulation in the iron sulfate family

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Article information

DOI
https://doi.org/10.1039/D2CC02242G
Article type
Communication
Submitted
20 Apr 2022
Accepted
25 May 2022
First published
06 Jun 2022

Chem. Commun., 2022,58, 7074-7077

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Perovskite-derived structure modulation in the iron sulfate family

Y. Lan, Q. Yan, X. Zhang, W. Yao, C. Wang, C. Lee, P. Lightfoot and Y. Tang, Chem. Commun., 2022, 58, 7074 DOI: 10.1039/D2CC02242G

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