Ferrocene-derived Fe-metalated porous organic polymer for the core planarity-triggered detoxification of chemical warfare agents

Ratul Paul; Chitra Sarkar; Manjari Jain; Shaojun Xu; Kashmiri Borah; Duy Quang Dao; Chih-Wen Pao; Saswata Bhattacharya; John Mondal

doi:10.1039/D2CC01785G

Ferrocene-derived Fe-metalated porous organic polymer for the core planarity-triggered detoxification of chemical warfare agents†

Ratul Paul,

‡^ab Chitra Sarkar,

‡^ab Manjari Jain,

‡^c Shaojun Xu,

^de Kashmiri Borah,

^f Duy Quang Dao,

^g Chih-Wen Pao,^h Saswata Bhattacharya

*^c and John Mondal

*^ab

Author affiliations

* Corresponding authors

^a Catalysis & Fine Chemicals Division, CSIR-Indian Institute of Chemical Technology, Uppal Road, Hyderabad 500007, India
E-mail: johnmondal@iict.res.in, johncuchem@gmail.com

^b Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

^c Department of Physics, Indian Institute of Technology Delhi Hauz Khas, New Delhi 110 016, India
E-mail: saswata@physics.iitd.ac.in

^d Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK

^e UK Catalysis Hub, Research Complex at Harwell, Rutherford Appleton Laboratory, Harwell, OX11 0FA, UK

^f Polymers & Functional Materials Division, CSIR-Indian Institute of Chemical Technology, Uppal Road, Hyderabad 500 007, India

^g Institute of research and development, Duy Tan University, Da Nang, Vietnam

^h National Synchrotron Radiation Research Center, 101 Hsin-Ann Road, Hsinchu 30076, Taiwan

Abstract

Herein, we demonstrate the successful construction of two Fe-metalated porous organic polymers having planar (Fe-Tt-POP) and non-planar (Fe-Rb-POP) geometry via the ternary copolymerization strategy for the catalytic oxidative decontamination of different sulfur-based mustard gas simulants (HD). Fe-Tt-POP exhibits superior catalytic performance for the oxidation of thioanisole (TA) in comparison with Fe-Rb-POP. Interestingly, this activity difference can be further explored by in situ operando DRIFTS and DFT computational studies.

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Article information

DOI: https://doi.org/10.1039/D2CC01785G
Article type: Communication
Submitted: 29 Mar 2022
Accepted: 23 May 2022
First published: 23 May 2022

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Chem. Commun., 2022,58, 7789-7792

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Ferrocene-derived Fe-metalated porous organic polymer for the core planarity-triggered detoxification of chemical warfare agents

R. Paul, C. Sarkar, M. Jain, S. Xu, K. Borah, D. Q. Dao, C. Pao, S. Bhattacharya and J. Mondal, Chem. Commun., 2022, 58, 7789 DOI: 10.1039/D2CC01785G

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Chemical Communications

Ferrocene-derived Fe-metalated porous organic polymer for the core planarity-triggered detoxification of chemical warfare agents†

Abstract

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Ferrocene-derived Fe-metalated porous organic polymer for the core planarity-triggered detoxification of chemical warfare agents

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