Pt-Modified MoO3 catalyst for the electrochemically selective CO hydrogenation of cinnamaldehyde

Jialu Wang; Meng Jin; Yiyang Sun; Haimin Zhang

doi:10.1039/D2CC01527G

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Pt-Modified MoO₃ catalyst for the electrochemically selective CO hydrogenation of cinnamaldehyde†

Jialu Wang,

^ab Meng Jin,^ab Yiyang Sun^c and Haimin Zhang

*^ab

Author affiliations

* Corresponding authors

^a Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Centre for Excellence in Nanoscience, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China
E-mail: zhanghm@issp.ac.cn

^b University of Science and Technology of China, Hefei 230026, China

^c Department of Materials Science and Engineering, College of Engineering, Yonsei University, Seoul 03722, Republic of Korea

Abstract

The electrocatalytic selective hydrogenation of biomass-derived molecules is an important approach for synthesizing value-added chemicals. Herein, we synthesized carbon-supported platinum-modified molybdenum oxide nanoparticles (Pt–MoO₃/C) to efficiently catalyze cinnamaldehyde (CAL) to cinnamyl alcohol. DFT results unveiled that the modified Pt regulated the surface electronic structure, favourable for the vertical adsorption of CAL.

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Supplementary information PDF (2069K)

Article information

DOI: https://doi.org/10.1039/D2CC01527G
Article type: Communication
Submitted: 17 Mar 2022
Accepted: 07 May 2022
First published: 08 May 2022

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Chem. Commun., 2022,58, 6721-6724

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Pt-Modified MoO₃ catalyst for the electrochemically selective CO hydrogenation of cinnamaldehyde

J. Wang, M. Jin, Y. Sun and H. Zhang, Chem. Commun., 2022, 58, 6721 DOI: 10.1039/D2CC01527G

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