Issue 29, 2022

From trihydroborates to bisborylenes: a route to dinuclear bisborylene complexes

Abstract

A new route for the synthesis of dinuclear bisborylene complexes was described. A series of novel diruthenium bisborylenes were prepared through unprecedented triple B–H oxidative addition of trihydroborates with concomitant hydrogen liberation. Conversion of trihydroborates to bisborylenes involved the formation of tris(σ-B–H) borate as the crucial intermediate stage.

Graphical abstract: From trihydroborates to bisborylenes: a route to dinuclear bisborylene complexes

Supplementary files

Article information

Article type
Communication
Submitted
22 Feb 2022
Accepted
14 Mar 2022
First published
15 Mar 2022

Chem. Commun., 2022,58, 4659-4662

From trihydroborates to bisborylenes: a route to dinuclear bisborylene complexes

Y. Wei and T. Wang, Chem. Commun., 2022, 58, 4659 DOI: 10.1039/D2CC01078J

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