BINOL blocks as accessible triplet state modulators in BODIPY dyes

Josué Jiménez; Ruth Prieto-Montero; Sergio Serrano; Patrycja Stachelek; Esther Rebollar; Beatriz L. Maroto; Florencio Moreno; Virginia Martinez-Martinez; Robert Pal; Inmaculada García-Moreno; Santiago de la Moya

doi:10.1039/D2CC00991A

BINOL blocks as accessible triplet state modulators in BODIPY dyes†

Josué Jiménez,^a Ruth Prieto-Montero,

^b Sergio Serrano,^a Patrycja Stachelek,^c Esther Rebollar,

^d Beatriz L. Maroto,

^a Florencio Moreno,

^a Virginia Martinez-Martinez,

^b Robert Pal,

^c Inmaculada García-Moreno*^d and Santiago de la Moya

*^a

Author affiliations

* Corresponding authors

^a Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, 28040, Madrid, Spain
E-mail: santmoya@ucm.es

^b Departamento de Química Física, Universidad del País Vasco-EHU, Apartado 644, 48080, Bilbao, Spain

^c Department of Chemistry, Durham University, Road, Durham DH1 3LE, Durham, UK

^d Departamento de Sistemas de Baja Dimensionalidad, Superficies y Materia Condensada, Instituto de Química Física “Rocasolano”, C.S.I.C., Serrano 119, 28006 Madrid, Spain
E-mail: i.garcia-moreno@iqfr.csic.es

Abstract

BINOL moieties of different electronic demand are useful blocks for enabling the photo-production and modulation of triplet excited states in readily-accesible BINOL-based O-BODIPY dyes from standard F-BODIPY precursors. The rapid and rational development of smarter triplet-enabling BODIPY dyes on the basis of this strategy (e.g., TADF biomarker 4a or room temperature phosphor 4g) paves the way for advancing photonic applications based on organic triplet photosensitizers.

Chemical Communications

BINOL blocks as accessible triplet state modulators in BODIPY dyes†

Abstract

Supplementary files

Article information

Download Citation

Permissions

BINOL blocks as accessible triplet state modulators in BODIPY dyes

Social activity

Search articles by author

Spotlight

Advertisements