Issue 19, 2022

Palladium-catalyzed rearrangement reaction to access 1-phenanthrol derivatives

Abstract

This manuscript describes an unusual Pd-catalyzed rearrangement reaction. It provides efficient access to 1-phenanthrol derivatives using allyloxy-tethered aryl iodides. This rearrangement process involves the cleavage of a C–I bond, a C–O bond and C–H bonds, and the formation of two C–C bonds in one-pot. It is likely that the key to the success of this rearrangement is via β-carbon elimination from a strained palladacycle.

Graphical abstract: Palladium-catalyzed rearrangement reaction to access 1-phenanthrol derivatives

Supplementary files

Article information

Article type
Communication
Submitted
20 Jan 2022
Accepted
07 Feb 2022
First published
08 Feb 2022

Chem. Commun., 2022,58, 3186-3189

Palladium-catalyzed rearrangement reaction to access 1-phenanthrol derivatives

C. Liu, W. Shi, Y. Ding, N. Zheng and Y. Liang, Chem. Commun., 2022, 58, 3186 DOI: 10.1039/D2CC00392A

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