Activation of O2 across a C(sp3)–C(sp3) bond

Rahul Kumar; Stefan Richter; Suvendu Maity; Pallavi Sarkar; Nicolas Chrysochos; Swapan K. Pati; Prasanta Ghosh; Carola Schulzke; Anukul Jana

doi:10.1039/D2CC00110A

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Activation of O₂ across a C(sp³)–C(sp³) bond†‡

Rahul Kumar,

^a Stefan Richter,^b Suvendu Maity,^c Pallavi Sarkar,^d Nicolas Chrysochos,

^a Swapan K. Pati,

*^d Prasanta Ghosh,

*^c Carola Schulzke

*^b and Anukul Jana

*^a

Author affiliations

* Corresponding authors

^a Tata Institute of Fundamental Research Hyderabad, Gopanpally, Hyderabad-500046, Telangana, India
E-mail: ajana@tifrh.res.in

^b Institut für Biochemie, Universität Greifswald, Felix-Hausdorff-Straße 4, D-17489 Greifswald, Germany
E-mail: carola.schulzke@uni-greifswald.de

^c Department of Chemistry, Ramakrishna Mission Residential College, Narendrapur, Kolkata-700103, India
E-mail: ghosh@pghosh.in

^d Theoretical Sciences Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Bangalore-560064, India
E-mail: pati@jncasr.ac.in

Abstract

The activation of atmospheric molecular dioxygen (O₂) is reported, which occurred across a C(sp³)–C(sp³) bond of a piperazine derivative without any catalyst at ambient conditions under the formation of 1,2,4,7-dioxadiazoctane, an 8-membered (larger-ring) cyclic organic peroxide.

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Article information

DOI: https://doi.org/10.1039/D2CC00110A
Article type: Communication
Submitted: 07 Jan 2022
Accepted: 14 Jan 2022
First published: 14 Jan 2022

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Chem. Commun., 2022,58, 3122-3125

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Activation of O₂ across a C(sp³)–C(sp³) bond

R. Kumar, S. Richter, S. Maity, P. Sarkar, N. Chrysochos, S. K. Pati, P. Ghosh, C. Schulzke and A. Jana, Chem. Commun., 2022, 58, 3122 DOI: 10.1039/D2CC00110A

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