Issue 17, 2022
From the journal:

Chemical Communications

TEMPO-mediated late stage photochemical hydroxylation of biaryl sulfonium salts†

Yue Zhao,a   Congjun Yu,a   Wenjing Liang,a   Iuliana L. Atodireseia  and  Frederic W. Patureau ORCID logo *a  

* Corresponding authors

a Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen 52074, Germany
E-mail: frederic.patureau@rwth-aachen.de
Web: https://www.patureau-oc-rwth-aachen.de

Abstract

The late stage photochemical hydroxylation of biaryl sulfonium salts was enabled with a TEMPO derivative as a simple oxygen source, in metal free conditions. The scope and mechanism of this exceptionally simple synthetic method, which constructs important arylated phenols from aromatic C–H bonds, are herein discussed.

Graphical abstract: TEMPO-mediated late stage photochemical hydroxylation of biaryl sulfonium salts

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Article information

DOI
https://doi.org/10.1039/D1CC07057F
Article type
Communication
Submitted
15 Dec 2021
Accepted
13 Jan 2022
First published
07 Feb 2022
This article is Open Access
Creative Commons BY license

Chem. Commun., 2022,58, 2846-2849

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TEMPO-mediated late stage photochemical hydroxylation of biaryl sulfonium salts

Y. Zhao, C. Yu, W. Liang, I. L. Atodiresei and F. W. Patureau, Chem. Commun., 2022, 58, 2846 DOI: 10.1039/D1CC07057F

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