Issue 10, 2022
From the journal:

Chemical Communications

Trapping reactions with highly unstable hydrides of antimony and bismuth†

Selina Schneidera  and  Carsten von Hänisch ORCID logo *a  

* Corresponding authors

a Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße, Marburg 35043, Germany
E-mail: haenisch@chemie.uni-marburg.de
Fax: +49-6421-2825653

Abstract

(Dipp2NacNac)Ga (Dipp2NacNac = HC{C(Me)N(Dipp)}2; Dipp = 2,6-iPr2C6H3) was used as a trapping reagent for the unstable compounds tBuSbH2 and MeBiH2 to yield (Dipp2NacNac)GaH(SbHtBu) (1) and {(Dipp2NacNac)GaH(BiMe)}2 (2). Moreover, its reactions with a row of alkylated or arylated dichloro-bismuthenes resulted in either bridged species or the formation of a dibismuthane.

Graphical abstract: Trapping reactions with highly unstable hydrides of antimony and bismuth

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Article information

DOI
https://doi.org/10.1039/D1CC06741A
Article type
Communication
Submitted
30 Nov 2021
Accepted
22 Dec 2021
First published
22 Dec 2021

Chem. Commun., 2022,58, 1522-1525

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Trapping reactions with highly unstable hydrides of antimony and bismuth

S. Schneider and C. von Hänisch, Chem. Commun., 2022, 58, 1522 DOI: 10.1039/D1CC06741A

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