Issue 4, 2022
From the journal:

Chemical Communications

Electron transitions in a Ce(iii)-catecholate metal–organic framework†

Julia G. Knapp, ORCID logo a   Debmalya Ray,b   Paul B. Calio,c   Megan C. Wasson, ORCID logo a   Thais R. Scott,c   Laura Gagliardic  and  Omar K. Farha ORCID logo *a  

* Corresponding authors

a Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Rd, Evanston IL, USA
E-mail: o-farha@northwestern.edu

b Department of Chemistry, Chemical Theory Center, and Minnesota Supercomputing Institute, University of Minnesota, Pleasant St SE, Minneapolis, MN 55455, USA

c Department of Chemistry, Pritzker School of Molecular Engineering, James Franck Institute, and Chicago Center for Theoretical Chemistry, the University of Chicago, 5735 S Ellis Ave, Chicago, IL 60637, USA

Abstract

A rare three-dimensional catecholate-based Ce(III) metal–organic framework (MOF), denoted as NU-1701, has been synthesized and crystallographically characterized. Density functional theory calculations highlight various possible electronic transitions that may present in NU-1701. These transitions are competitive and indicate increased lanthanide character of Ce(III).

Graphical abstract: Electron transitions in a Ce(iii)-catecholate metal–organic framework

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Article information

DOI
https://doi.org/10.1039/D1CC06440A
Article type
Communication
Submitted
15 Nov 2021
Accepted
08 Dec 2021
First published
15 Dec 2021

Chem. Commun., 2022,58, 525-528

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Electron transitions in a Ce(III)-catecholate metal–organic framework

J. G. Knapp, D. Ray, P. B. Calio, M. C. Wasson, T. R. Scott, L. Gagliardi and O. K. Farha, Chem. Commun., 2022, 58, 525 DOI: 10.1039/D1CC06440A

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