Issue 5, 2022

Organometallic Ni(ii), Ni(iii), and Ni(iv) complexes relevant to carbon–carbon and carbon–oxygen bond formation reactions

Abstract

Herein, the pyridinophanetetradentate ligand 3,6,9-trimethyl-3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene, PyNMe3, is used to isolate and structurally characterize well-defined organometallic Ni(II) and Ni(III) complexes bearing the cycloneophyl fragment, an alkyl/aryl C-donor ligand. Furthermore, spectroscopic and cryo-mass spectrometry studies suggest the formation of a transient Ni(IV) organometallic complex, and its relevance to C–C and C–O bond formation reactivity studies is discussed.

Graphical abstract: Organometallic Ni(ii), Ni(iii), and Ni(iv) complexes relevant to carbon–carbon and carbon–oxygen bond formation reactions

Supplementary files

Article information

Article type
Research Article
Submitted
27 Nov 2021
Accepted
13 Jan 2022
First published
13 Jan 2022

Inorg. Chem. Front., 2022,9, 1016-1022

Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon–carbon and carbon–oxygen bond formation reactions

C. Magallón, L. Griego, C. H. Hu, A. Company, X. Ribas and L. M. Mirica, Inorg. Chem. Front., 2022, 9, 1016 DOI: 10.1039/D1QI01486B

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