Merging the chemistry of metal–organic and polyoxometalate clusters to form enhanced photocatalytic materials

Jon Napal; Beñat Artetxe; Garikoitz Beobide; Oscar Castillo; Antonio Luque; Jon Pascual-Colino; Sonia Pérez-Yáñez; Maite Perfecto-Irigaray

doi:10.1039/D1QI01411K

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Merging the chemistry of metal–organic and polyoxometalate clusters to form enhanced photocatalytic materials†

Jon Napal,

^a Beñat Artetxe,

^a Garikoitz Beobide,

*^ab Oscar Castillo,

*^ab Antonio Luque,

^ab Jon Pascual-Colino,

^a Sonia Pérez-Yáñez

^cb and Maite Perfecto-Irigaray

Author affiliations

* Corresponding authors

^a Department of Organic and Inorganic Chemistry, University of the Basque Country, UPV/EHU, P.O. 644, E-48080 Bilbao, Spain
E-mail: oscar.castillo@ehu.eus, garikoitz.beobide@ehu.eus

^b BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, E-48940 Leioa, Spain

^c Department of Organic and Inorganic Chemistry, University of the Basque Country, UPV/EHU, E-01006 Vitoria-Gasteiz, Spain

Abstract

The combination of a zirconium metal–organic cluster and a Keggin type polyoxotungstate into a compound of the formula [Zr₆(μ₃-O)₄(μ₃-OH)₄(μ-OOCC₆H₅)₈(H₂O)₈][SiW₁₂O₄₀] led to a chemically and photochemically stable material in which a synergistic effect between the metal–organic cluster and the polyoxometalate allows marked enhancement of the photochemical activity of the single ionic components toward the photooxidation of dyes.

This article is part of the themed collection: FOCUS: Design and applications of metal-organic frameworks (MOFs)

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DOI: https://doi.org/10.1039/D1QI01411K
Article type: Research Article
Submitted: 08 Nov 2021
Accepted: 11 Jan 2022
First published: 17 Jan 2022

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Inorg. Chem. Front., 2022,9, 935-940

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Merging the chemistry of metal–organic and polyoxometalate clusters to form enhanced photocatalytic materials

J. Napal, B. Artetxe, G. Beobide, O. Castillo, A. Luque, J. Pascual-Colino, S. Pérez-Yáñez and M. Perfecto-Irigaray, Inorg. Chem. Front., 2022, 9, 935 DOI: 10.1039/D1QI01411K

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Inorganic Chemistry Frontiers

Merging the chemistry of metal–organic and polyoxometalate clusters to form enhanced photocatalytic materials†

Abstract

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Merging the chemistry of metal–organic and polyoxometalate clusters to form enhanced photocatalytic materials

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