Issue 80, 2022

Two-photon, red light uncaging of alkyl radicals from organorhodium(iii) phthalocyanine complexes

Abstract

A stepwise two-photon, red light excitation of organorhodium(III) phthalocyanine complexes was found to induce the activation of the axial metal–carbon bond to generate alkyl radicals/aldehydes. The cooperative action of the photouncaging reaction and the photochemical generation of reactive oxygen species were indicated to induce the cell deaths.

Graphical abstract: Two-photon, red light uncaging of alkyl radicals from organorhodium(iii) phthalocyanine complexes

Supplementary files

Article information

Article type
Communication
Submitted
01 Jul 2022
Accepted
18 Aug 2022
First published
20 Sep 2022

Chem. Commun., 2022,58, 11280-11283

Two-photon, red light uncaging of alkyl radicals from organorhodium(III) phthalocyanine complexes

K. Murata, Y. Saibe, M. Uchida, M. Aono, R. Misawa, Y. Ikeuchi and K. Ishii, Chem. Commun., 2022, 58, 11280 DOI: 10.1039/D2CC03672J

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