Synthesis of the two isomers of heteroleptic Rh12L6L′6 metal–organic polyhedra by screening of complementary linkers

Abstract

We have synthesised and characterised the two possible isomers of heteroleptic trigonal antiprismatic M12L6L′6 MOPs by screening reactions of rhodium acetate with different pairs of complementary dicarboxylate linkers. The resulting 12 new MOPs (eight of isomer A + four of isomer B) are microporous in the solid state, exhibiting Brunauer–Emmett–Teller (BET) surface areas as high as 770 m2 g−1.

Graphical abstract: Synthesis of the two isomers of heteroleptic Rh12L6L′6 metal–organic polyhedra by screening of complementary linkers

Supplementary files

Article information

Article type
Communication
Submitted
07 Jun 2022
Accepted
16 Jul 2022
First published
19 Jul 2022

Chem. Commun., 2022, Advance Article

Synthesis of the two isomers of heteroleptic Rh12L6L′6 metal–organic polyhedra by screening of complementary linkers

A. Broto-Ribas, M. S. Gutiérrez, I. Imaz, A. Carné-Sánchez, F. Gándara, J. Juanhuix and D. Maspoch, Chem. Commun., 2022, Advance Article , DOI: 10.1039/D2CC03220A

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