Issue 38, 2022

A cyclic divalent N(i) species isoelectronic to carbodiphosphoranes

Abstract

The formation of a rare type of diphosphazenium cation is described. Its synthesis features a unique oxidative dealkylation of an iminophosphorane-phosphole by a silver(I) salt. DFT study of this compound reveals the low valent character of the N(I) center.

Graphical abstract: A cyclic divalent N(i) species isoelectronic to carbodiphosphoranes

Supplementary files

Article information

Article type
Communication
Submitted
22 Mar 2022
Accepted
14 Apr 2022
First published
18 Apr 2022

Chem. Commun., 2022,58, 5741-5744

A cyclic divalent N(I) species isoelectronic to carbodiphosphoranes

J. Tian, M. Cordier, C. Bour, A. Auffrant and V. Gandon, Chem. Commun., 2022, 58, 5741 DOI: 10.1039/D2CC01637K

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