Issue 11, 2022

Concurrent base and silver(i) catalysis pulsed by fuel acid

Abstract

Treatment of a crown-ether receptor and a silver(I)-loaded cyclam derivative ([double bond, length as m-dash]NetState-I) with a fuel acid reversibly afforded the protonated cyclam and the silver(I)-loaded crown ether ([double bond, length as m-dash]NetState-II). While NetState-I was catalytically OFF, a base-catalysed Michael addition and a silver(I)-catalysed oxime cyclisation reaction was pulsed under dissipative conditions in NetState-II.

Graphical abstract: Concurrent base and silver(i) catalysis pulsed by fuel acid

Supplementary files

Article information

Article type
Communication
Submitted
12 Nov 2021
Accepted
06 Jan 2022
First published
07 Jan 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2022,58, 1728-1731

Concurrent base and silver(I) catalysis pulsed by fuel acid

I. Valiyev, A. Ghosh, I. Paul and M. Schmittel, Chem. Commun., 2022, 58, 1728 DOI: 10.1039/D1CC06398G

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