Remarkable thermoelectric property enhancement in Cu2SnS3–CuCo2S4 nanocomposites via 3D modulation doping

Abstract

P-type ternary sulfide Cu₂SnS₃ and CuCo₂S₄ with merits of low toxicity, natural abundance and intrinsically low lattice thermal conductivity are considered as promising eco-friendly thermoelectric materials. Here, we report a remarkable thermoelectric property enhancement in a Cu₂SnS₃-based nanocomposite material with the incorporation of 5 mol% CuCo₂S₄. Like the traditional modulation doping approach, in such a two-phase nanocomposite, charge carriers are mainly derived from the CuCo₂S₄ (metal-like) phase and transferred to the Cu₂SnS₃ (semiconductor) phase enabled by an appropriate band alignment. Results reveal that such a hetero-structure can simultaneously improve the unsatisfactory carrier concentration of both the phases to a moderate level and also maintain the high carrier mobility of pristine Cu₂SnS₃, contributing to an increased power factor of ∼10 μW cm⁻¹ K⁻² at 773 K. Meanwhile, the homogeneous distribution of the nanoscale minor phase can effectively impede phonon transport and results in a suppressed lattice thermal conductivity of ∼0.5 W m⁻¹ K⁻¹ at 773 K. Ultimately, a high ZT ∼ 0.83 has been achieved at 773 K which is comparable with that of the best Cu₂SnS₃-based material obtained by cobalt doping.