Supramolecular fibrous gels with helical pitch tunable by polarity of alcohol solvents

Abstract

A sugar-based, low-molecular-weight gelator 16AG, can gelatinize primary alcohols by forming supramolecular fibers. We obtained non-helical, tape-like fibers in methanol and ethanol but helical fibers in alcohols with at least three carbons. The pitch of the helical fibers became shorter with increasing carbon number.