Issue 18, 2021

Ambient microdroplet annealing of nanoparticles


Conversion of polydisperse nanoparticles to their monodisperse analogues and formation of organized superstructures using them involve post synthetic modifications, and the process is generally slow. We show that ambient electrospray of preformed polydisperse nanoparticles makes them monodisperse and the product nanoparticles self-assemble spontaneously to form organized films, all within seconds. This phenomenon has been demonstrated with thiol-protected polydisperse silver nanoparticles of 15 ± 10 nm diameter. Uniform silver nanoparticles of 4.0 ± 0.5 nm diameter were formed after microdroplet spray, and this occurred without added chemicals, templates, and temperature, and within the time needed for electrospray, which was of the order of seconds. Well organized nanoparticle assemblies were obtained from such uniform particles. A home-made and simple nanoelectrospray set-up produced charged microdroplets for the generation of such nanostructures, forming cm2 areas of uniform nanoparticles. A free-standing thin film of monodisperse silver nanoparticles was also made on a liquid surface by controlling the electrospray conditions. This unique method may be extended for the creation of advanced materials of many kinds.

Graphical abstract: Ambient microdroplet annealing of nanoparticles

Supplementary files

Article information

Article type
Edge Article
08 Jan 2021
24 Mar 2021
First published
24 Mar 2021
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2021,12, 6370-6377

Ambient microdroplet annealing of nanoparticles

A. Ray Chowdhuri, B. K. Spoorthi, B. Mondal, P. Bose, S. Bose and T. Pradeep, Chem. Sci., 2021, 12, 6370 DOI: 10.1039/D1SC00112D

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