Issue 53, 2021, Issue in Progress

Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof

Abstract

Lithium anions derived from O-carbonate-protected cyanohydrins undergo conjugate addition to cycloalkenones with the concomitant transfer of the alkoxycarbonyl group to produce tricarbonyl compounds. These products offer numerous possibilities for further elaboration. The synthetic potential of the cascade products was demonstrated by forming bicyclic and tricyclic systems through intramolecular condensation reactions.

Graphical abstract: Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof

Supplementary files

Article information

Article type
Paper
Submitted
05 Jul 2021
Accepted
28 Sep 2021
First published
11 Oct 2021
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2021,11, 33235-33244

Consecutive reactions to construct tricarbonyl compounds and synthetic applications thereof

D. Madroñero, C. A. Mujica-Martinez and A. Vázquez, RSC Adv., 2021, 11, 33235 DOI: 10.1039/D1RA05187C

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