Novel sustainable materials from waste plastics: compatibilized blend from discarded bale wrap and plastic bottles

Abstract

This work studies a novel sustainable polymeric material made from a reactive blend of two agri-food waste plastics, with the new material showing strong promise for value-added industrial uses. Discarded bale wrap destined for landfill that was originally made from linear low density polyethylene (LLDPE) and used polyethylene terephthalate (PET)-based plastic bottles were melt mixed in a twin-screw extruder. The miscibility of such recycled LLDPE (rLLDPE) in recycled PET (rPET) is enhanced by the incorporation of a compatibilizer and the PET molecular architecture is maintained using a chain extender, which governs its melt strength. Microscopic analysis of the blends with the compatibilizer and chain extender confirms the enhanced interaction of rPET and rLLDPE chains and the formation of co-continuous morphologies. The efficient interaction of a soft phase (rLLDPE) with a hard phase (rPET) leads to prolonged fracture propagation by an appropriate impact energy transfer mechanism, which ultimately enhances the impact resistance and elongation at break of the resulting blend. The incorporation of a compatibilizer and chain extender in the rPET/rLLDPE blend makes it a toughened blend (with 60 J m⁻¹ notched Izod impact strength) with ∼80% elongation at break in comparison to ∼3% for the blend without a compatibilizer or chain extender. Around ∼36% enhancement is observed in the tensile strength without affecting the tensile and flexural modulus in comparison to the blend without a compatibilizer or chain extender. Applications of the developed materials can extend from rigid packaging applications to the production of filaments for 3D printing.