Removal of mercury from polluted water by a novel composite of polymer carbon nanofiber: kinetic, isotherm, and thermodynamic studies

Abstract

This work aims at the synthesis of a polymer of poly-trimesoyl chloride and polyethyleneimine grafted on carbon fibers (PCF) derived from palm. The obtained PCF was characterized using Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX) for its structural properties. The obtained PCF was then evaluated for the removal of mercury (Hg(II)) from aqueous solutions using batch adsorption studies at four different temperatures (298, 308, 318, and 328 K). The experimental parameters such as initial concentration, pH, dosage, and contact time were optimized on the mercury adsorption. The percentage removal was 100% with an adsorbent dosage of 100 mg L⁻¹ at a pH between 5 and 7 and temperature of 298 K and thus kinetic, isotherm, and thermodynamic studies were performed under these conditions. By the Langmuir adsorption isotherm, the maximum adsorption capacity of Hg(II) by PCF was 19.2 mg g⁻¹. In addition, results fit the pseudo-second-order model, with R² > 0.99, to describe the adsorption kinetic mechanism. The adsorption process is spontaneous with an endothermic nature under the studied conditions.