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Friedel-Crafts acylation of antiaromatic norcorrole: electronic and steric modulation of the paratropic current

Abstract

Acyl chlorides react with norcorrolatonickle(II) in dichloromethane in the presence of AlCl3 at room temperature affording two isomeric monoketone derivatives in moderate yields. For acetyl chloride, also diketones were detected and separated. Spectroscopic and electrochemical characterization were corroborated by DFT calculations.

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Article information


Submitted
21 Apr 2021
Accepted
07 Jun 2021
First published
07 Jun 2021

Org. Chem. Front., 2021, Accepted Manuscript
Article type
Research Article

Friedel-Crafts acylation of antiaromatic norcorrole: electronic and steric modulation of the paratropic current

S. Li, O. Smaga, Y. Sun, X. Li, M. Pawlicki, M. Sukniewicz and P. J. Chmielewski, Org. Chem. Front., 2021, Accepted Manuscript , DOI: 10.1039/D1QO00621E

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