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Abstract | Cited by

A new dynamic C–Se bond-based addition–fragmentation chain transfer (AFCT) reaction of allyl selenides was performed under irradiation without any catalyst. ESR data and theoretical results indicated that the transfer reaction proceeded through a radical mechanism. This new dynamic bond holds great potential for application in smart polymer materials.

Graphical abstract: Photoresponsive dynamic covalent bond based on addition–fragmentation chain transfer of allyl selenides

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