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Issue 10, 2021
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The mass spectrometric fragmentation mechanisms of catenulane and isocatenulane diterpenes

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Abstract

Two new diterpene derivatives were obtained by semisynthesis from enzymatically generated catenul-14-en-6-ol. The EI-MS fragmentation mechanisms of three enzyme products and the two semisynthetic derivatives were investigated by extensive 13C-labelling experiments.

Graphical abstract: The mass spectrometric fragmentation mechanisms of catenulane and isocatenulane diterpenes

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Article information


Submitted
27 Jan 2021
Accepted
18 Feb 2021
First published
18 Feb 2021

Org. Biomol. Chem., 2021,19, 2224-2232
Article type
Paper

The mass spectrometric fragmentation mechanisms of catenulane and isocatenulane diterpenes

G. Li, Y. Guo and J. S. Dickschat, Org. Biomol. Chem., 2021, 19, 2224
DOI: 10.1039/D1OB00160D

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