Exploration of Kobayashi's aryne precursor: a potent reactive platform for the synthesis of polycyclic aromatic hydrocarbons

Manashi Sarmah; Abhilash Sharma; Pranjal Gogoi

doi:10.1039/D0OB02063J

Exploration of Kobayashi's aryne precursor: a potent reactive platform for the synthesis of polycyclic aromatic hydrocarbons

Manashi Sarmah,^a Abhilash Sharma^ab and Pranjal Gogoi

*^ab

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* Corresponding authors

^a Applied Organic Chemistry Group, Chemical Science and Technology Division, CSIR-North East Institute of Science and Technology, Jorhat 785006, Assam, India
E-mail: gogoipranj@yahoo.co.uk

^b Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

Abstract

Arynes due to their transient nature leads to remarkable and versatile applications in the synthetic world. Apparently, researchers have focused on the construction of simple to complex π-conjugated systems using arynes as the reactive platform. In this regard, Kobayashi's aryne precursor has shown a great extent of reactivity and afforded significant advancement in the synthesis of polycyclic aromatic systems with wide practical utility. This review emphasizes the extensive utilization of Kobayashi's aryne intermediates and their derivatives for the synthesis of different classes of polycyclic aromatic hydrocarbons (PAHs).

This article is part of the themed collection: Synthetic methodology in OBC

Article information

Submitted

09 Oct 2020

Accepted

16 Dec 2020

First published

16 Dec 2020

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Org. Biomol. Chem., 2021,19, 722-737

Article type

Review Article

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Exploration of Kobayashi's aryne precursor: a potent reactive platform for the synthesis of polycyclic aromatic hydrocarbons

M. Sarmah, A. Sharma and P. Gogoi, Org. Biomol. Chem., 2021, 19, 722

DOI: 10.1039/D0OB02063J

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Exploration of Kobayashi's aryne precursor: a potent reactive platform for the synthesis of polycyclic aromatic hydrocarbons

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Exploration of Kobayashi's aryne precursor: a potent reactive platform for the synthesis of polycyclic aromatic hydrocarbons

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